Here is just a little proof that "GM does set the stoich ratio to 14.1".
I understand the 14.7 parts air to 1 part fuel for 100% gasoline, it's just that they do not use 100% gasoline in the calibrations anymore because everything can be up to E10 at the pump on regular 87 octane.
GM doesn't set a +/- for the fuel trims, there is no table within the calibration for that.
As said the 02 sensors/fuel trims only report what is going on in the exhaust. These are narrowband o2 sensors and .450mv is what we consider to be stoich. The sensors will show it swinging lean and rich of that value and the trims will show you the work being done to reach that. Be it a negative value or trimming fuel or positive value of adding fuel in real time on the fly.
The main problem I have with people running these mixes is that there is far more to the picture than just what the o2 sensors do. When the E85 sensor shows a higher alcohol content in the fuel, it's changing the commanded stoich or lambda value in the tune. Which also changes the injector functions and timing, it would also change the timing and commanded fueling under certain loads and full throttle. That is stuff that can't be controlled when it doesn't know what is going on.