Higher octane gas does not have more additives. Additives will vary between brands of gas, but not octane levels within the same brand. For example, Shell 87, 89, and 93 all have the same amount of additives in the fuel. The difference is the octane rating between the three which can affect engine performance as lower octane is more likely to produce engine knock due to the high compression ratios of these engines. Engine knock, whether you can hear it or not, will cause the engine and computer to compensate for the knock which reduces horse power and fuel economy. So yes you should use higher octane gas when towing but not because it runs cooler or has more additives, but because you get better performance out of your engine since the fuel is less likely to cause engine knock. As Fondupot pointed out, per Black Bear Performance, they detect engine knock on 87 in these trucks and reccomend a minimum of 89 on even a stock tuning because of the high compression ratio of these engines. Check out Black Bear's FAQ's here: http://www.blackbearperformance.com/faqs.asp
Getting back to additives, they will vary between brands. A top tier brand like Shell will have more cleaning additives than a non top tier brand like say Sunoco. For more info on Top Tier gas go here: http://www.toptiergas.com/